2-(3-Nitrophenyl)-4,5-diphenyl-1H-imidazol-3-ium chloride
نویسنده
چکیده
The title compound, C(21)H(16)N(3)O(2) (+)·Cl(-), contains two organic cations with similar conformation and two chloride ions in the asymmetric unit. The imidazole and benzene rings are twisted with respect to each other [dihedral angles of 24.05 (16), 24.31 (16) and 50.38 (13) in one cation and 27.70 (15), 25.07 (16) and 45.86 (14)° in the other]. The crystal packing is stabilized by N-H⋯Cl hydrogen bonds, forming an infinite one-dimensional chain parallel to the c axis.
منابع مشابه
2-(4-Nitrophenyl)-4,5-diphenyl-1H-imidazol-3-ium chloride
In the cation of the title compound, C(21)H(16)N(3)O(2) (+)·Cl(-), the N atom in the 3-position of the imidazole ring is protonated. The three pendant aromatic rings are twisted from the plane of the imidazolium ring by dihedral angles of 31.69 (14)°, 31.09 (14)° and 34.77 (14)°. In the crystal structure, N-H⋯Cl hydrogen bonds link the mol-ecules, forming a chain parallel to the b axis.
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An atom-economic synthetic route to benzimidazolium salts is presented. The annulated polycyclic systems: 1,3-bis(2,4,6-trimethylphenyl)-1H-benzo[d]imidazol-3-ium chloride (1-Cl), 1,3-bis(2,6-diisopropylphenyl)-1H-benzo[d]imidazol-3-ium chloride (2-Cl), 1,3-diphenyl-1H-benzo[d]imidazol-3-ium chloride (3-Cl), and 1,3-di(pyridin-2-yl)-1H-benzo[d]imidazol-3-ium chloride (4-Cl) were prepared in a t...
متن کامل2-(3-Nitrophenyl)-4,5-diphenyl-1H-imidazol-3-ium nitrate
In the cation of the title compound, C(21)H(16)N(3)O(2) (+)·NO(3) (-), the N atom in the 3-position of the imidazole ring is protonated. The three pendant aromatic rings are twisted from the plane of the imidazolium ring by dihedral angles of 22.75 (1), 79.63 (1) and 29.65 (1)°. In the crystal structure, N-H⋯O hydrogen bonds link the mol-ecules, forming an infinite one-dimensional chain paralle...
متن کامل4,5-Diphenyl-2-p-tolyl-1H-imidazol-3-ium perchlorate
In the title compound, C(22)H(19)N(2) (+)·ClO(4) (-), the three pendant aromatic rings are twisted from the plane of the imidazolium ring by dihedral angles of 17.3 (2), 65.7 (2) and 3.4 (2)°. In the crystal structure, N-H⋯O and N-H⋯(O,O) hydrogen bonds link the ions, forming a ribbon-like structure along the a axis.
متن کامل2-Amino-1-methyl-4-oxo-4,5-dihydro-1H-imidazol-3-ium chloride
In the crystal structure of the title compound, C(4)H(8)N(3)O(+)·Cl(-), N-H⋯Cl hydrogen bonds link the components into chains along [010]. In addition, weak C-H⋯Cl hydrogen bonds link the chains into a two-dimensional network perpendicular to (001).
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